6.2 Temperature Coefficient of Resistance
Key Takeaways
Pure metallic conductors exhibit a Positive Temperature Coefficient (PTC), meaning electrical resistance increases as temperature rises due to intensified lattice ion vibrations impeding electron drift.
Semiconductors, carbon, electrolytes, and negative temperature coefficient (NTC) thermistors show decreasing resistance with rising temperature as thermal energy releases additional charge carriers into conduction bands.
Specialized alloys such as Constantan and Manganin feature near-zero temperature coefficients, making them indispensable for precision instrument shunts and laboratory reference standards.
The mathematical relationship governing temperature-induced resistance changes is , where represents the fractional resistance change per degree Celsius.
In BS 7671 verification, copper conductor resistance increases by approximately 20% (1.20 multiplier) between a ambient test and full operating temperature, establishing the 0.8 test rule of thumb.
Temperature Coefficient of Resistance
In electrotechnical systems, electrical resistance is never strictly constant across operating environments. As an electrical machine, luminaire, or distribution cable carries current, it undergoes thermal changes due to internal power dissipation and fluctuations in ambient air temperature. The degree to which a material's electrical resistance changes in response to temperature variations depends directly on its atomic structure and is characterized by its temperature coefficient of resistance (symbolized by the Greek letter alpha, ).
Understanding how temperature alters resistance is fundamental for practicing electricians. Cable current-carrying capacities, voltage drop thresholds, motor winding diagnostics, and statutory earth fault loop impedance () verification all depend on precise thermal adjustments.
Material Classifications: PTC, NTC, and Zero-Coefficient Alloys
Materials fall into three broad categories based on how their electrical resistance responds to temperature:
1. Positive Temperature Coefficient (PTC) — Pure Metals
All pure metals used in electrical installation work—such as copper, aluminium, silver, gold, and tungsten—possess a Positive Temperature Coefficient (PTC). For these materials, an increase in temperature produces an increase in electrical resistance.
- Microscopic Mechanism: In a metallic conductor, valence electrons are delocalized, forming an "electron gas" that drifts through a rigid crystalline lattice of positive atomic ions. At low temperatures, these lattice ions vibrate with relatively small amplitudes around their fixed equilibrium positions, allowing conduction electrons to drift with infrequent collisions (a longer "mean free path"). As temperature rises, thermal energy causes the positive lattice ions to vibrate with greater velocity and larger amplitudes. These intensified vibrations increase the cross-sectional collision frequency between drifting electrons and the lattice, impeding charge drift velocity and raising bulk electrical resistance.
2. Negative Temperature Coefficient (NTC) — Carbon and Semiconductors
Materials with a Negative Temperature Coefficient (NTC) exhibit an inverse response: as temperature increases, electrical resistance decreases.
- Microscopic Mechanism: In materials such as carbon (graphite), semiconductors (silicon and germanium), metallic oxide thermistors, and liquid electrolytes, valence electrons are tightly bound within covalent bonds at room temperature, leaving few charge carriers available in the conduction band. As thermal energy is supplied, covalent bonds are broken, releasing exponential cascades of free electrons and positive holes into the conduction band. This massive increase in the density of available charge carriers far outweighs the minor increase in lattice collision scattering, resulting in a dramatic net decrease in electrical resistance.
- Practical Applications: NTC thermistors are widely utilized as temperature sensors in electronic thermostats, boiler water temperature monitors, digital thermometers, and inrush-current limiters that safely suppress initial current spikes in power supplies.
3. Zero or Negligible Temperature Coefficient Alloys
Specialized metallic alloys have been engineered to exhibit virtually zero change in electrical resistance across wide working temperature ranges:
- Constantan (Eureka): Composed of 55% copper and 45% nickel, Constantan has a temperature coefficient of approximately (essentially zero).
- Manganin: Composed of 84% copper, 12% manganese, and 4% nickel, Manganin exhibits a temperature coefficient of roughly .
- Engineering Importance: When constructing precision measurement instruments—such as ammeter shunts, voltmeter multipliers, Wheatstone bridges, and calibrated resistance decade boxes—resistor values must remain invariant regardless of whether ambient room temperature fluctuates or internal current flow generates heat. Using pure copper for an ammeter shunt would cause the meter calibration to drift by roughly 4% for every rise; zero-coefficient alloys eliminate this thermal error.
| Material Class | Typical Materials | Response to Rising Temperature () | Temperature Coefficient ( at ) | Typical Electrotechnical Application |
|---|---|---|---|---|
| PTC (Pure Metals) | Annealed Copper | Resistance Increases | () | Power distribution cables, motor field coils, busbars. |
| PTC (Pure Metals) | Aluminium | Resistance Increases | () | Overhead lines, large sub-main distribution cables. |
| PTC (Pure Metals) | Tungsten | Resistance Increases Strongly | () | Incandescent lamps (resistance increases to when lit). |
| NTC (Semiconductors) | Carbon (Graphite) | Resistance Decreases | () | Motor commutator brushes, arc furnace electrodes. |
| NTC (Oxide Ceramics) | NTC Thermistor | Resistance Decreases Sharply | Up to () | Central heating thermistors, motor thermal overload probes. |
| Near-Zero Alloys | Constantan & Manganin | Resistance Remains Constant | (Negligible) | Ammeter current shunts, precision calibration standards. |
Mathematical Calculation of Temperature Variations
The temperature coefficient of resistance () is defined as the fractional change in electrical resistance per degree Celsius () change in temperature from a given baseline temperature.
The Reference Temperature Formula
When calculating final resistance from a baseline reference temperature of :
Where:
- = Conductor resistance at operating temperature ()
- = Conductor resistance at ()
- = Temperature coefficient of the material at ()
- = Conductor temperature in degrees Celsius ()
The Practical Working Temperature Formula
In electrical contracting, baseline tests are rarely conducted at . Instead, measurements are typically taken at ambient workshop temperature (standardized as ). To calculate the resistance at a second operating temperature :
Where:
- = Initial resistance at temperature ()
- = Final resistance at temperature ()
- = Temperature coefficient at initial temperature (for copper at , , often rounded to )
- = Temperature rise in degrees Celsius ()
Worked Example 1: Contactor Coil Hot Resistance
Problem: The copper field coil of an AC contactor has a resistance of when measured in an unenergized panel at . After six hours of continuous energization under heavy factory load, the coil temperature stabilizes at . Calculate the operating resistance of the coil, taking .
Solution:
- Identify known values:
- Substitute into the formula:
- Evaluate bracket terms:
- Calculate final resistance:
Worked Example 2: Temperature Rise Diagnostic in an Electric Motor
Problem: During machine maintenance, an induction motor stator winding has a cold resistance of at an ambient room temperature of . Following a 4-hour full-load thermal run, the hot winding resistance measures . Determine the final operating temperature of the winding, taking .
Solution:
- Transpose the equation for temperature rise :
- Substitute measured values:
- Calculate final temperature :
The BS 7671 Rule of Thumb: The 20% Increase and the 0.8 Factor
In practical UK electrical installation inspection and testing under BS 7671 (IET Wiring Regulations), temperature variations have direct statutory safety implications. This is most critical when verifying earth fault loop impedance ().
The Operational Problem
- Initial Verification Testing: Carried out before an installation is energized and loaded, under cold ambient site conditions—typically assumed to be .
- Full-Load Operating State: When an installation carries design current (), continuous power dissipation heats the copper conductors to their maximum permissible continuous operating temperature:
- for standard thermoplastic (PVC) insulated cables.
- for thermosetting (XLPE / LSOH) insulated cables.
The 20% Resistance Increase Multiplier
To determine how much copper conductor resistance increases between ambient testing () and maximum thermoplastic operating temperature ():
Important
The electrical resistance of copper conductors increases by approximately 20% (a multiplier of ) as temperature rises from a ambient dead-test condition to a maximum continuous full-load operating temperature of .
The 0.8 Rule-of-Thumb Factor for Maximum Verification
To ensure that protective devices (such as BS EN 60898 circuit breakers or BS 88 fuses) disconnect automatically within the required statutory time limits ( for final circuits up to ), the operating earth fault loop impedance must not exceed the maximum values published in BS 7671 and the IET On-Site Guide ().
However, the maximum values published in BS 7671 are calculated for conductors operating at their maximum operating temperature of . If an electrician measures at , the measured reading will naturally be lower than the impedance during a live fault under load.
To confirm compliance during initial testing at ambient temperatures, the electrician can:
- Multiply the measured ambient loop impedance by to project its value at :
- Or, divide both sides by to compare the measured value directly against a reduced limit:
To provide an additional safety margin covering supply voltage variations and earthing conductor variations, BS 7671 and the IET On-Site Guide specify a conservative 0.80 multiplier (known as the "rule-of-thumb factor"):
If a 32 A Type B MCB has a tabulated maximum of in BS 7671, the maximum permissible reading on an instrument at is:
What microscopic mechanism causes the electrical resistance of pure copper conductors to increase as temperature rises?
Conduction electrons recombine into covalent bonds, reducing carrier availability
Thermal expansion reduces the physical cross-sectional area of the conductor core
Positive lattice ions vibrate with larger amplitudes, increasing electron collision frequency
The copper conductor undergoes rapid atmospheric surface oxidation
Which of the following materials is specifically chosen for constructing precision ammeter shunts and laboratory standard resistors because its resistance does not change with temperature?
Constantan (Eureka)
High-conductivity annealed copper
Hard-drawn pure aluminium
Graphite carbon
A copper solenoid coil has an electrical resistance of 15.0 Ω at 20°C. Taking the temperature coefficient of copper as 0.00393 per °C, what is the coil's resistance when operating at 75°C?
15.82 Ω
16.50 Ω
20.25 Ω
18.24 Ω
When verifying measured earth fault loop impedance (Zs) at an ambient temperature of 20°C against the maximum tabulated values in BS 7671 for 70°C thermoplastic cables, which rule-of-thumb factor is applied to the tabulated maximum?
1.20
0.80
0.50
1.00
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