3.2 General Science — Chemistry & Everyday Materials
Key Takeaways
- Pure water is neutral at pH 7; acids lie below 7 and turn blue litmus red, while bases lie above 7 and turn red litmus blue.
- Common-name chemistry is high-yield: baking soda is sodium bicarbonate (NaHCO3), washing soda is sodium carbonate decahydrate, bleaching powder is calcium hypochlorite and quicklime is calcium oxide.
- The three primary fertiliser nutrients are nitrogen, phosphorus and potassium (NPK); urea is the most widely used nitrogen fertiliser at about 46% nitrogen.
- Diamond is the hardest natural form of carbon and graphite is a good conductor, even though both are pure carbon — a difference of structure, not composition.
- Hard water contains dissolved calcium and magnesium salts, which is why it wastes soap and forms scale in kettles and boilers.
Chemistry — Key Concepts
Matter and Its States
| State | Property |
|---|---|
| Solid | Definite shape and volume; particles tightly packed |
| Liquid | Definite volume, takes container shape; particles loosely packed |
| Gas | No definite shape or volume; particles far apart |
State changes: melting (solid→liquid), evaporation (liquid→gas), condensation (gas→liquid), freezing (liquid→solid), sublimation (solid→gas directly).
Atoms and Molecules
- Atom — smallest particle of an element that retains its properties
- Molecule — two or more atoms chemically bonded
- Atomic number (Z) = number of protons
- Mass number (A) = protons + neutrons
- Isotopes — same atomic number, different mass number (e.g., ¹H, ²H, ³H)
Acids, Bases, Salts and pH
| Substance | pH Range | Litmus Effect |
|---|---|---|
| Acid | < 7 | Turns blue litmus red |
| Neutral | = 7 | No change |
| Base | > 7 | Turns red litmus blue |
- Strong acids: HCl, H₂SO₄, HNO₃
- Strong bases: NaOH, KOH
- Common salts: NaCl (common salt), CaCO₃ (limestone), NaHCO₃ (baking soda)
Chemical Reactions
| Type | Example |
|---|---|
| Combination | A + B → AB |
| Decomposition | AB → A + B |
| Displacement | A + BC → AC + B |
| Double displacement | AB + CD → AD + CB |
| Oxidation-reduction (redox) | transfer of electrons; oxidation = loss, reduction = gain |
Periodic Table Basics
- Groups = vertical columns (1–18); elements in a group have similar outer electron configuration
- Periods = horizontal rows (1–7); atomic number increases left to right
- Alkali metals (Group 1): Li, Na, K — highly reactive
- Halogens (Group 17): F, Cl, Br, I — reactive non-metals
- Noble gases (Group 18): He, Ne, Ar — inert
Carbon Compounds
- Allotropes of carbon — diamond (hardest natural), graphite (conductor), fullerene, graphene
- Hydrocarbons — alkanes (single bond), alkenes (double bond), alkynes (triple bond)
- Functional groups — alcohol (-OH), aldehyde (-CHO), carboxylic acid (-COOH)
- Ethanol (C₂H₅OH) — used in alcoholic drinks and as fuel
- Ethanoic acid (CH₃COOH) — vinegar (5–8% solution)
Metals and Non-Metals
| Property | Metals | Non-metals |
|---|---|---|
| Appearance | Lustrous | Mostly dull |
| Conductivity | Good conductors of heat and electricity | Poor conductors (graphite is the exception) |
| Malleable / ductile | Yes | No — brittle when solid |
| Oxides | Basic | Acidic |
| At room temperature | Solid, except mercury (liquid) | Solid, liquid (bromine) or gas |
- Reactivity series (most to least reactive): K, Na, Ca, Mg, Al, Zn, Fe, Pb, Cu, Ag, Au. A more reactive metal displaces a less reactive one from its salt solution — iron nails placed in copper sulphate solution turn brown and the blue solution fades.
- Rusting of iron needs both oxygen and moisture; it is prevented by painting, oiling, galvanising (zinc coating) or alloying into stainless steel.
- Alloys to remember: brass (copper + zinc), bronze (copper + tin), steel (iron + carbon), stainless steel (iron + chromium + nickel), solder (lead + tin).
- Noble metals — gold, silver, platinum — resist corrosion, which is why they occur in native form.
Everyday Chemicals — Common Name to Formula
| Common name | Chemical name | Formula | Everyday use |
|---|---|---|---|
| Common salt | Sodium chloride | NaCl | Food; raw material for chlor-alkali industry |
| Baking soda | Sodium hydrogen carbonate | NaHCO₃ | Baking, antacid, fire extinguishers |
| Washing soda | Sodium carbonate decahydrate | Na₂CO₃·10H₂O | Cleaning, softening hard water |
| Bleaching powder | Calcium oxychloride / hypochlorite | CaOCl₂ | Disinfecting drinking water |
| Quicklime | Calcium oxide | CaO | Whitewashing, cement, soil treatment |
| Slaked lime | Calcium hydroxide | Ca(OH)₂ | Whitewash, neutralising acidic soil |
| Gypsum | Calcium sulphate dihydrate | CaSO₄·2H₂O | Cement, plaster of Paris, soil conditioner |
| Blue vitriol | Copper sulphate | CuSO₄·5H₂O | Fungicide (Bordeaux mixture) |
| Marsh gas | Methane | CH₄ | Biogas, gobar gas plants |
Water Quality — Directly Relevant to Village Work
- Hard water contains dissolved calcium and magnesium salts. It wastes soap by forming scum and deposits scale in kettles and boilers. Soft water lathers easily.
- Temporary hardness (bicarbonates) is removed by boiling; permanent hardness (sulphates and chlorides) needs washing soda or an ion-exchange resin.
- Drinking water is disinfected by chlorination (bleaching powder) or boiling. Excess fluoride in groundwater causes fluorosis — a real problem in parts of north Karnataka — and excess arsenic or nitrate contamination also arises from groundwater.
- Water pollution indicators: high BOD (biochemical oxygen demand) means heavy organic load; eutrophication is nutrient enrichment causing algal blooms, as seen in Bengaluru's lakes.
Fertilisers, Soil Chemistry and Crops
- Plants need three primary nutrients — nitrogen (N) for leaf growth, phosphorus (P) for roots and flowering, potassium (K) for overall vigour and disease resistance.
- Urea — CO(NH₂)₂, about 46% nitrogen — is the most widely used nitrogen fertiliser in India. DAP supplies nitrogen and phosphorus; MOP (muriate of potash) supplies potassium.
- Acidic soil is corrected by adding lime; alkaline or saline soil is treated with gypsum. A VAO recording soil type and irrigation source on the RTC is, in effect, recording the inputs a soil-health question would ask about.
- Biofertilisers — Rhizobium in legume root nodules, Azotobacter, blue-green algae — fix atmospheric nitrogen biologically. Compost and green manure improve organic carbon.
Exam Angle for Chemistry
Chemistry questions in this paper are overwhelmingly definitional or common-name based. Three habits cover most of them: memorise the pH and litmus rules in one line each; keep a running common name to formula to use table like the one above; and learn the reactivity series as a spoken sentence so displacement questions become instant. Balancing equations and stoichiometry are effectively never asked at this level, so do not spend time there.
What is the pH value of a neutral solution such as pure water at 25°C?
Which pair correctly matches the common name to its chemical name?
A farmer reports that soap does not lather in the village well water and the kettle has a thick white deposit. What is the most likely cause?
Urea is the most widely used nitrogen fertiliser in India. Approximately what percentage of nitrogen does it contain?