15.1 Material Identification: Ferrous & Non-Ferrous Metals, Plastics

Key Takeaways

  • In the AISI/SAE four-digit system the last two digits give carbon content in hundredths of a percent, so 1045 is a plain carbon steel with 0.45% carbon and 4140 is a chrome-moly steel with 0.40% carbon.
  • Austenitic 300-series stainless steel is non-magnetic in the annealed condition, while ferritic and martensitic 400-series stainless steels are magnetic — the fastest field discriminator.
  • Only steels above roughly 0.30% carbon will harden appreciably by quenching, which is why low-carbon structural steel cannot be hardened but can be case hardened.
  • Spark testing reads carbon content: low-carbon steel throws long straw streaks with few forks, high-carbon steel throws dense repeating bursts, and cast iron throws short dull red streaks.
  • Positive material identification with a portable X-ray fluorescence analyzer is the only definitive field method for alloy verification on code work.
Last updated: August 2026

Sub-task A-3.06 (Performs material identification) sits inside Task A-3, which carries 7 of the 25 questions in Major Work Activity A. Selecting the wrong material for a shaft, a wear plate or a repair weld is a failure that shows up weeks later, so the exam tests whether a journeyperson can classify what is in front of them.

The AISI / SAE Numbering System

Plain carbon and alloy steels use a four-digit designation:

DigitsMeaning
First digitMajor alloy family — 1 carbon, 2 nickel, 3 nickel-chromium, 4 molybdenum, 5 chromium, 6 chromium-vanadium, 8 nickel-chrome-moly, 9 silicon-manganese
Second digitApproximate percentage of the principal alloying element, or a sub-class
Last two digitsCarbon content in hundredths of one percent
GradeReads asTypical millwright use
1018Plain carbon, 0.18% CGeneral shafting, machine parts, weldable, case-hardens well
1045Plain carbon, 0.45% CMedium-carbon shafting, keys, gears; through-hardenable
4140Chrome-moly, 0.40% CHigh-strength shafts, bolts, hydraulic rams — the workhorse alloy steel
4340Ni-Cr-Mo, 0.40% CHeavily loaded shafts and gears
8620Ni-Cr-Mo, 0.20% CCarburizing grade for gears and pins
52100High-carbon chromium, 1.00% CRolling-element bearing steel (also called 100Cr6)

Carbon Ranges and Their Consequence

ClassCarbonBehaviour
Low carbon (mild)Under 0.30%Readily welded and formed; does not harden appreciably by quenching; case-harden instead
Medium carbon0.30–0.60%Through-hardenable; needs preheat for welding above about 0.35%
High carbon0.60–1.00%Springs, cutting edges, wear parts; difficult to weld, high cracking risk
Tool steel0.70%+ with alloysWater-hardening (W), oil-hardening (O), air-hardening (A), high-speed (M, T)

The rule that follows is worth memorizing: weldability falls and hardenability rises as carbon content rises. A shaft that hardens under a torch flame is a medium- or high-carbon steel, and welding it without preheat will crack it.

Cast Irons

TypeStructureCharacteristics
Grey cast ironGraphite flakesExcellent damping and machinability; brittle in tension; machine bases, housings, pump casings
Ductile (nodular) ironSpheroidal graphiteMuch higher tensile strength and impact resistance; crankshafts, gears, valve bodies
White cast ironCementite, no free graphiteExtremely hard and abrasion resistant; unmachinable; wear liners
Malleable ironHeat-treated white ironDuctile and shock resistant; pipe fittings, brackets

Grey iron is identified by a dull grey fracture face that leaves a grey mark on your hand from the graphite, whereas steel fractures bright.

Stainless Steels

FamilySeriesMagnetic?Notes
Austenitic300 (304, 316, 321)Non-magnetic when annealed (can become slightly magnetic after cold work)Cannot be hardened by heat treatment, only by cold work; 316 adds molybdenum for chloride resistance
Ferritic400 (409, 430)MagneticModerate corrosion resistance; not hardenable by quenching
Martensitic400 (410, 416, 420, 440)MagneticHardenable by quench and temper; shafts, valve stems, cutlery
Duplex2205, 2507MagneticAustenite plus ferrite; high strength and chloride-stress-corrosion resistance
Precipitation hardening17-4 PHMagneticVery high strength; pump and valve shafts

The magnet is the fastest field test: a shaft that a magnet will not stick to, in a corrosive service, is almost certainly 304 or 316. That matters immediately because austenitic grades cannot be hardened by heat treatment and are prone to galling on threads unless anti-seize is used.

Non-Ferrous Metals and Bearing Alloys

MetalIdentificationUse
AluminumLight (about one third the weight of steel), non-magnetic, grey oxideGuards, light structures; 6061-T6 is the general machining grade
CopperReddish, very high conductivityElectrical, tubing, gaskets
Brass (Cu-Zn)YellowFittings, bushings, valve internals
Bronze (Cu-Sn)Reddish-brown; harder than brassSleeve bearings, wear plates, worm gears
Babbitt (tin or lead based)Very soft, silverPoured or lined plain bearings; embeds dirt and protects the shaft
Monel (Ni-Cu)Grey, non-magnetic to weakly magnetic, very toughSeawater and chemical service
TitaniumVery light, extremely tough, sparks bright whiteChemical process, aggressive corrosion

Aluminum temper designations appear constantly on machine parts: -O annealed, -Hxx strain hardened (non-heat-treatable alloys), -T4 solution treated and naturally aged, -T6 solution treated and artificially aged (the common structural condition).

Engineering Plastics and Composites

Millwrights increasingly install plastic wear components, chain guides and bearings.

MaterialKey propertyTypical application
UHMW-PEExtremely low friction, high abrasion resistance, self-lubricatingChain guides, wear strips, chute liners, star wheels
Nylon (PA)Tough, absorbs moisture and swellsSheaves, bushings, gears
Acetal (POM / Delrin)Dimensionally stable, low moisture absorption, machines cleanlyPrecision bushings and gears
PTFELowest friction, chemically inert, poor creep resistanceSeals, non-stick surfaces, chemical service
PEEKHigh temperature (to about 250 C), high strengthDemanding bearings and seals
HDPEChemically resistant, weldableTanks, piping, liners
Fibreglass (FRP)Corrosion resistant, non-conductiveGratings, tanks, ducting

Plastic bearing selection trap: nylon absorbs moisture and can swell by 2–3%, so a nylon bushing machined to a tight clearance in a dry shop will seize once it is wet. Acetal or UHMW is used where dimensional stability matters.

Field Identification Tests

TestMethodWhat it tells you
MagnetTouch a magnet to a clean surfaceSeparates austenitic stainless (non-magnetic) from carbon and 400-series steel (magnetic)
SparkTouch to a grinding wheel in a darkened area and read the streamCarbon content and alloy family
FileDraw a sharp file across an edgeSoft material cuts easily; hardened material skates and will not cut
ChipCut a chip with a cold chiselDuctile materials give a continuous curl; cast iron gives short brittle chips
Appearance and weightColour, oxide, densityDistinguishes aluminum, copper alloys, and cast iron
Sound (ring test)Suspend and strikeA cracked casting or roll gives a dull thud instead of a ring
Hardness testRockwell, Brinell, or portable hardness testerConfirms heat-treated condition
PMI / portable XRFX-ray fluorescence analyzerThe only definitive field alloy verification; required on code piping and pressure work

Reading a Spark Test

   WROUGHT IRON      Long straight straw-yellow streaks, forked ends, no bursts
   LOW-CARBON STEEL  Long straw streaks with a few small forks near the end
   MEDIUM CARBON     More numerous forks and small starbursts along the stream
   HIGH-CARBON STEEL Dense, bright, repeating multi-branch bursts near the wheel
   CAST IRON         Short, dull RED streaks that brighten and burst near the end
   STAINLESS (300)   Short, straw-coloured stream, few forks, less brilliant
   HIGH-SPEED STEEL  Faint dark red stream with distinctive orange spear points

Spark testing is a comparison method: keep known reference samples at the grinder and compare. It gives a family, not a grade.

Mechanical Properties the Exam Uses

PropertyDefinitionPractical meaning
Tensile strengthMaximum stress before fractureUltimate capacity of a shaft or bolt
Yield strengthStress at which permanent deformation beginsThe real design limit — a bolt stretched past yield loses preload
DuctilityElongation percentage before fractureAbility to deform rather than snap
HardnessResistance to indentationCorrelates with wear resistance and tensile strength in steel
ToughnessEnergy absorbed before fracture (Charpy impact)Resistance to shock, especially at low temperature
Fatigue strengthStress a part survives for a set number of cyclesGoverns rotating shafts; a sharp corner or keyway is a fatigue initiator

Hardness scales: Rockwell C (HRC) for hardened steel above about 20 HRC, Rockwell B (HRB) for softer steels and non-ferrous, and Brinell (HB) for castings and large sections using a 10 mm ball at 3,000 kg. A shaft specified at 28–32 HRC is a quenched-and-tempered medium-carbon or alloy steel, not mild steel.

Low-temperature toughness is a Canadian issue. Ordinary carbon steel undergoes a ductile-to-brittle transition as temperature falls; structural and lifting components used outdoors in winter must be specified with notch-toughness requirements. Hoisting a load with a shackle or lifting lug made from an unrated steel at -30 C risks brittle fracture with no warning.

Test Your Knowledge

A millwright must replace a broken drive shaft. The old shaft is marked 4140, a magnet sticks strongly to it, and a file will barely cut the surface. What does this tell them about the material and its repair?

A
B
C
D
Test Your Knowledge

A pump shaft in a chloride-bearing process is non-magnetic and the maintenance history says it was ordered as 316. The plant wants it hardened to reduce sleeve wear. What is the correct response?

A
B
C
D
Test Your Knowledge

A millwright machines a nylon bushing to a tight running clearance in a dry heated shop, and it seizes on the shaft two weeks after installation in a wash-down area. What material property explains the failure?

A
B
C
D