15.1 Material Identification: Ferrous & Non-Ferrous Metals, Plastics
Key Takeaways
- In the AISI/SAE four-digit system the last two digits give carbon content in hundredths of a percent, so 1045 is a plain carbon steel with 0.45% carbon and 4140 is a chrome-moly steel with 0.40% carbon.
- Austenitic 300-series stainless steel is non-magnetic in the annealed condition, while ferritic and martensitic 400-series stainless steels are magnetic — the fastest field discriminator.
- Only steels above roughly 0.30% carbon will harden appreciably by quenching, which is why low-carbon structural steel cannot be hardened but can be case hardened.
- Spark testing reads carbon content: low-carbon steel throws long straw streaks with few forks, high-carbon steel throws dense repeating bursts, and cast iron throws short dull red streaks.
- Positive material identification with a portable X-ray fluorescence analyzer is the only definitive field method for alloy verification on code work.
Sub-task A-3.06 (Performs material identification) sits inside Task A-3, which carries 7 of the 25 questions in Major Work Activity A. Selecting the wrong material for a shaft, a wear plate or a repair weld is a failure that shows up weeks later, so the exam tests whether a journeyperson can classify what is in front of them.
The AISI / SAE Numbering System
Plain carbon and alloy steels use a four-digit designation:
| Digits | Meaning |
|---|---|
| First digit | Major alloy family — 1 carbon, 2 nickel, 3 nickel-chromium, 4 molybdenum, 5 chromium, 6 chromium-vanadium, 8 nickel-chrome-moly, 9 silicon-manganese |
| Second digit | Approximate percentage of the principal alloying element, or a sub-class |
| Last two digits | Carbon content in hundredths of one percent |
| Grade | Reads as | Typical millwright use |
|---|---|---|
| 1018 | Plain carbon, 0.18% C | General shafting, machine parts, weldable, case-hardens well |
| 1045 | Plain carbon, 0.45% C | Medium-carbon shafting, keys, gears; through-hardenable |
| 4140 | Chrome-moly, 0.40% C | High-strength shafts, bolts, hydraulic rams — the workhorse alloy steel |
| 4340 | Ni-Cr-Mo, 0.40% C | Heavily loaded shafts and gears |
| 8620 | Ni-Cr-Mo, 0.20% C | Carburizing grade for gears and pins |
| 52100 | High-carbon chromium, 1.00% C | Rolling-element bearing steel (also called 100Cr6) |
Carbon Ranges and Their Consequence
| Class | Carbon | Behaviour |
|---|---|---|
| Low carbon (mild) | Under 0.30% | Readily welded and formed; does not harden appreciably by quenching; case-harden instead |
| Medium carbon | 0.30–0.60% | Through-hardenable; needs preheat for welding above about 0.35% |
| High carbon | 0.60–1.00% | Springs, cutting edges, wear parts; difficult to weld, high cracking risk |
| Tool steel | 0.70%+ with alloys | Water-hardening (W), oil-hardening (O), air-hardening (A), high-speed (M, T) |
The rule that follows is worth memorizing: weldability falls and hardenability rises as carbon content rises. A shaft that hardens under a torch flame is a medium- or high-carbon steel, and welding it without preheat will crack it.
Cast Irons
| Type | Structure | Characteristics |
|---|---|---|
| Grey cast iron | Graphite flakes | Excellent damping and machinability; brittle in tension; machine bases, housings, pump casings |
| Ductile (nodular) iron | Spheroidal graphite | Much higher tensile strength and impact resistance; crankshafts, gears, valve bodies |
| White cast iron | Cementite, no free graphite | Extremely hard and abrasion resistant; unmachinable; wear liners |
| Malleable iron | Heat-treated white iron | Ductile and shock resistant; pipe fittings, brackets |
Grey iron is identified by a dull grey fracture face that leaves a grey mark on your hand from the graphite, whereas steel fractures bright.
Stainless Steels
| Family | Series | Magnetic? | Notes |
|---|---|---|---|
| Austenitic | 300 (304, 316, 321) | Non-magnetic when annealed (can become slightly magnetic after cold work) | Cannot be hardened by heat treatment, only by cold work; 316 adds molybdenum for chloride resistance |
| Ferritic | 400 (409, 430) | Magnetic | Moderate corrosion resistance; not hardenable by quenching |
| Martensitic | 400 (410, 416, 420, 440) | Magnetic | Hardenable by quench and temper; shafts, valve stems, cutlery |
| Duplex | 2205, 2507 | Magnetic | Austenite plus ferrite; high strength and chloride-stress-corrosion resistance |
| Precipitation hardening | 17-4 PH | Magnetic | Very high strength; pump and valve shafts |
The magnet is the fastest field test: a shaft that a magnet will not stick to, in a corrosive service, is almost certainly 304 or 316. That matters immediately because austenitic grades cannot be hardened by heat treatment and are prone to galling on threads unless anti-seize is used.
Non-Ferrous Metals and Bearing Alloys
| Metal | Identification | Use |
|---|---|---|
| Aluminum | Light (about one third the weight of steel), non-magnetic, grey oxide | Guards, light structures; 6061-T6 is the general machining grade |
| Copper | Reddish, very high conductivity | Electrical, tubing, gaskets |
| Brass (Cu-Zn) | Yellow | Fittings, bushings, valve internals |
| Bronze (Cu-Sn) | Reddish-brown; harder than brass | Sleeve bearings, wear plates, worm gears |
| Babbitt (tin or lead based) | Very soft, silver | Poured or lined plain bearings; embeds dirt and protects the shaft |
| Monel (Ni-Cu) | Grey, non-magnetic to weakly magnetic, very tough | Seawater and chemical service |
| Titanium | Very light, extremely tough, sparks bright white | Chemical process, aggressive corrosion |
Aluminum temper designations appear constantly on machine parts: -O annealed, -Hxx strain hardened (non-heat-treatable alloys), -T4 solution treated and naturally aged, -T6 solution treated and artificially aged (the common structural condition).
Engineering Plastics and Composites
Millwrights increasingly install plastic wear components, chain guides and bearings.
| Material | Key property | Typical application |
|---|---|---|
| UHMW-PE | Extremely low friction, high abrasion resistance, self-lubricating | Chain guides, wear strips, chute liners, star wheels |
| Nylon (PA) | Tough, absorbs moisture and swells | Sheaves, bushings, gears |
| Acetal (POM / Delrin) | Dimensionally stable, low moisture absorption, machines cleanly | Precision bushings and gears |
| PTFE | Lowest friction, chemically inert, poor creep resistance | Seals, non-stick surfaces, chemical service |
| PEEK | High temperature (to about 250 C), high strength | Demanding bearings and seals |
| HDPE | Chemically resistant, weldable | Tanks, piping, liners |
| Fibreglass (FRP) | Corrosion resistant, non-conductive | Gratings, tanks, ducting |
Plastic bearing selection trap: nylon absorbs moisture and can swell by 2–3%, so a nylon bushing machined to a tight clearance in a dry shop will seize once it is wet. Acetal or UHMW is used where dimensional stability matters.
Field Identification Tests
| Test | Method | What it tells you |
|---|---|---|
| Magnet | Touch a magnet to a clean surface | Separates austenitic stainless (non-magnetic) from carbon and 400-series steel (magnetic) |
| Spark | Touch to a grinding wheel in a darkened area and read the stream | Carbon content and alloy family |
| File | Draw a sharp file across an edge | Soft material cuts easily; hardened material skates and will not cut |
| Chip | Cut a chip with a cold chisel | Ductile materials give a continuous curl; cast iron gives short brittle chips |
| Appearance and weight | Colour, oxide, density | Distinguishes aluminum, copper alloys, and cast iron |
| Sound (ring test) | Suspend and strike | A cracked casting or roll gives a dull thud instead of a ring |
| Hardness test | Rockwell, Brinell, or portable hardness tester | Confirms heat-treated condition |
| PMI / portable XRF | X-ray fluorescence analyzer | The only definitive field alloy verification; required on code piping and pressure work |
Reading a Spark Test
WROUGHT IRON Long straight straw-yellow streaks, forked ends, no bursts
LOW-CARBON STEEL Long straw streaks with a few small forks near the end
MEDIUM CARBON More numerous forks and small starbursts along the stream
HIGH-CARBON STEEL Dense, bright, repeating multi-branch bursts near the wheel
CAST IRON Short, dull RED streaks that brighten and burst near the end
STAINLESS (300) Short, straw-coloured stream, few forks, less brilliant
HIGH-SPEED STEEL Faint dark red stream with distinctive orange spear points
Spark testing is a comparison method: keep known reference samples at the grinder and compare. It gives a family, not a grade.
Mechanical Properties the Exam Uses
| Property | Definition | Practical meaning |
|---|---|---|
| Tensile strength | Maximum stress before fracture | Ultimate capacity of a shaft or bolt |
| Yield strength | Stress at which permanent deformation begins | The real design limit — a bolt stretched past yield loses preload |
| Ductility | Elongation percentage before fracture | Ability to deform rather than snap |
| Hardness | Resistance to indentation | Correlates with wear resistance and tensile strength in steel |
| Toughness | Energy absorbed before fracture (Charpy impact) | Resistance to shock, especially at low temperature |
| Fatigue strength | Stress a part survives for a set number of cycles | Governs rotating shafts; a sharp corner or keyway is a fatigue initiator |
Hardness scales: Rockwell C (HRC) for hardened steel above about 20 HRC, Rockwell B (HRB) for softer steels and non-ferrous, and Brinell (HB) for castings and large sections using a 10 mm ball at 3,000 kg. A shaft specified at 28–32 HRC is a quenched-and-tempered medium-carbon or alloy steel, not mild steel.
Low-temperature toughness is a Canadian issue. Ordinary carbon steel undergoes a ductile-to-brittle transition as temperature falls; structural and lifting components used outdoors in winter must be specified with notch-toughness requirements. Hoisting a load with a shackle or lifting lug made from an unrated steel at -30 C risks brittle fracture with no warning.
A millwright must replace a broken drive shaft. The old shaft is marked 4140, a magnet sticks strongly to it, and a file will barely cut the surface. What does this tell them about the material and its repair?
A pump shaft in a chloride-bearing process is non-magnetic and the maintenance history says it was ordered as 316. The plant wants it hardened to reduce sleeve wear. What is the correct response?
A millwright machines a nylon bushing to a tight running clearance in a dry heated shop, and it seizes on the shaft two weeks after installation in a wash-down area. What material property explains the failure?