15.1 Material Identification: Ferrous & Non-Ferrous Metals, Plastics
Key Takeaways
In the AISI/SAE four-digit system the last two digits give carbon content in hundredths of a percent, so 1045 is a plain carbon steel with 0.45% carbon and 4140 is a chrome-moly steel with 0.40% carbon.
Austenitic 300-series stainless steel is non-magnetic in the annealed condition, while ferritic and martensitic 400-series stainless steels are magnetic — the fastest field discriminator.
Only steels above roughly 0.30% carbon will harden appreciably by quenching, which is why low-carbon structural steel cannot be hardened but can be case hardened.
Spark testing reads carbon content: low-carbon steel throws long straw streaks with few forks, high-carbon steel throws dense repeating bursts, and cast iron throws short dull red streaks.
Positive material identification with a portable X-ray fluorescence analyzer is the only definitive field method for alloy verification on code work.
Sub-task A-3.06 (Performs material identification) sits inside Task A-3, which carries 7 of the 25 questions in Major Work Activity A. Selecting the wrong material for a shaft, a wear plate or a repair weld is a failure that shows up weeks later, so the exam tests whether a journeyperson can classify what is in front of them.
The AISI / SAE Numbering System
Plain carbon and alloy steels use a four-digit designation:
| Digits | Meaning |
|---|---|
| First digit | Major alloy family — 1 carbon, 2 nickel, 3 nickel-chromium, 4 molybdenum, 5 chromium, 6 chromium-vanadium, 8 nickel-chrome-moly, 9 silicon-manganese |
| Second digit | Approximate percentage of the principal alloying element, or a sub-class |
| Last two digits | Carbon content in hundredths of one percent |
| Grade | Reads as | Typical millwright use |
|---|---|---|
| 1018 | Plain carbon, 0.18% C | General shafting, machine parts, weldable, case-hardens well |
| 1045 | Plain carbon, 0.45% C | Medium-carbon shafting, keys, gears; through-hardenable |
| 4140 | Chrome-moly, 0.40% C | High-strength shafts, bolts, hydraulic rams — the workhorse alloy steel |
| 4340 | Ni-Cr-Mo, 0.40% C | Heavily loaded shafts and gears |
| 8620 | Ni-Cr-Mo, 0.20% C | Carburizing grade for gears and pins |
| 52100 | High-carbon chromium, 1.00% C | Rolling-element bearing steel (also called 100Cr6) |
Carbon Ranges and Their Consequence
| Class | Carbon | Behaviour |
|---|---|---|
| Low carbon (mild) | Under 0.30% | Readily welded and formed; does not harden appreciably by quenching; case-harden instead |
| Medium carbon | 0.30–0.60% | Through-hardenable; needs preheat for welding above about 0.35% |
| High carbon | 0.60–1.00% | Springs, cutting edges, wear parts; difficult to weld, high cracking risk |
| Tool steel | 0.70%+ with alloys | Water-hardening (W), oil-hardening (O), air-hardening (A), high-speed (M, T) |
The rule that follows is worth memorizing: weldability falls and hardenability rises as carbon content rises. A shaft that hardens under a torch flame is a medium- or high-carbon steel, and welding it without preheat will crack it.
Cast Irons
| Type | Structure | Characteristics |
|---|---|---|
| Grey cast iron | Graphite flakes | Excellent damping and machinability; brittle in tension; machine bases, housings, pump casings |
| Ductile (nodular) iron | Spheroidal graphite | Much higher tensile strength and impact resistance; crankshafts, gears, valve bodies |
| White cast iron | Cementite, no free graphite | Extremely hard and abrasion resistant; unmachinable; wear liners |
| Malleable iron | Heat-treated white iron | Ductile and shock resistant; pipe fittings, brackets |
Grey iron is identified by a dull grey fracture face that leaves a grey mark on your hand from the graphite, whereas steel fractures bright.
Stainless Steels
| Family | Series | Magnetic? | Notes |
|---|---|---|---|
| Austenitic | 300 (304, 316, 321) | Non-magnetic when annealed (can become slightly magnetic after cold work) | Cannot be hardened by heat treatment, only by cold work; 316 adds molybdenum for chloride resistance |
| Ferritic | 400 (409, 430) | Magnetic | Moderate corrosion resistance; not hardenable by quenching |
| Martensitic | 400 (410, 416, 420, 440) | Magnetic | Hardenable by quench and temper; shafts, valve stems, cutlery |
| Duplex | 2205, 2507 | Magnetic | Austenite plus ferrite; high strength and chloride-stress-corrosion resistance |
| Precipitation hardening | 17-4 PH | Magnetic | Very high strength; pump and valve shafts |
The magnet is the fastest field test: a shaft that a magnet will not stick to, in a corrosive service, is almost certainly 304 or 316. That matters immediately because austenitic grades cannot be hardened by heat treatment and are prone to galling on threads unless anti-seize is used.
Non-Ferrous Metals and Bearing Alloys
| Metal | Identification | Use |
|---|---|---|
| Aluminum | Light (about one third the weight of steel), non-magnetic, grey oxide | Guards, light structures; 6061-T6 is the general machining grade |
| Copper | Reddish, very high conductivity | Electrical, tubing, gaskets |
| Brass (Cu-Zn) | Yellow | Fittings, bushings, valve internals |
| Bronze (Cu-Sn) | Reddish-brown; harder than brass | Sleeve bearings, wear plates, worm gears |
| Babbitt (tin or lead based) | Very soft, silver | Poured or lined plain bearings; embeds dirt and protects the shaft |
| Monel (Ni-Cu) | Grey, non-magnetic to weakly magnetic, very tough | Seawater and chemical service |
| Titanium | Very light, extremely tough, sparks bright white | Chemical process, aggressive corrosion |
Aluminum temper designations appear constantly on machine parts: -O annealed, -Hxx strain hardened (non-heat-treatable alloys), -T4 solution treated and naturally aged, -T6 solution treated and artificially aged (the common structural condition).
Engineering Plastics and Composites
Millwrights increasingly install plastic wear components, chain guides and bearings.
| Material | Key property | Typical application |
|---|---|---|
| UHMW-PE | Extremely low friction, high abrasion resistance, self-lubricating | Chain guides, wear strips, chute liners, star wheels |
| Nylon (PA) | Tough, absorbs moisture and swells | Sheaves, bushings, gears |
| Acetal (POM / Delrin) | Dimensionally stable, low moisture absorption, machines cleanly | Precision bushings and gears |
| PTFE | Lowest friction, chemically inert, poor creep resistance | Seals, non-stick surfaces, chemical service |
| PEEK | High temperature (to about 250 C), high strength | Demanding bearings and seals |
| HDPE | Chemically resistant, weldable | Tanks, piping, liners |
| Fibreglass (FRP) | Corrosion resistant, non-conductive | Gratings, tanks, ducting |
Plastic bearing selection trap: nylon absorbs moisture and can swell by 2–3%, so a nylon bushing machined to a tight clearance in a dry shop will seize once it is wet. Acetal or UHMW is used where dimensional stability matters.
Field Identification Tests
| Test | Method | What it tells you |
|---|---|---|
| Magnet | Touch a magnet to a clean surface | Separates austenitic stainless (non-magnetic) from carbon and 400-series steel (magnetic) |
| Spark | Touch to a grinding wheel in a darkened area and read the stream | Carbon content and alloy family |
| File | Draw a sharp file across an edge | Soft material cuts easily; hardened material skates and will not cut |
| Chip | Cut a chip with a cold chisel | Ductile materials give a continuous curl; cast iron gives short brittle chips |
| Appearance and weight | Colour, oxide, density | Distinguishes aluminum, copper alloys, and cast iron |
| Sound (ring test) | Suspend and strike | A cracked casting or roll gives a dull thud instead of a ring |
| Hardness test | Rockwell, Brinell, or portable hardness tester | Confirms heat-treated condition |
| PMI / portable XRF | X-ray fluorescence analyzer | The only definitive field alloy verification; required on code piping and pressure work |
Reading a Spark Test
WROUGHT IRON Long straight straw-yellow streaks, forked ends, no bursts
LOW-CARBON STEEL Long straw streaks with a few small forks near the end
MEDIUM CARBON More numerous forks and small starbursts along the stream
HIGH-CARBON STEEL Dense, bright, repeating multi-branch bursts near the wheel
CAST IRON Short, dull RED streaks that brighten and burst near the end
STAINLESS (300) Short, straw-coloured stream, few forks, less brilliant
HIGH-SPEED STEEL Faint dark red stream with distinctive orange spear points
Spark testing is a comparison method: keep known reference samples at the grinder and compare. It gives a family, not a grade.
Mechanical Properties the Exam Uses
| Property | Definition | Practical meaning |
|---|---|---|
| Tensile strength | Maximum stress before fracture | Ultimate capacity of a shaft or bolt |
| Yield strength | Stress at which permanent deformation begins | The real design limit — a bolt stretched past yield loses preload |
| Ductility | Elongation percentage before fracture | Ability to deform rather than snap |
| Hardness | Resistance to indentation | Correlates with wear resistance and tensile strength in steel |
| Toughness | Energy absorbed before fracture (Charpy impact) | Resistance to shock, especially at low temperature |
| Fatigue strength | Stress a part survives for a set number of cycles | Governs rotating shafts; a sharp corner or keyway is a fatigue initiator |
Hardness scales: Rockwell C (HRC) for hardened steel above about 20 HRC, Rockwell B (HRB) for softer steels and non-ferrous, and Brinell (HB) for castings and large sections using a 10 mm ball at 3,000 kg. A shaft specified at 28–32 HRC is a quenched-and-tempered medium-carbon or alloy steel, not mild steel.
Low-temperature toughness is a Canadian issue. Ordinary carbon steel undergoes a ductile-to-brittle transition as temperature falls; structural and lifting components used outdoors in winter must be specified with notch-toughness requirements. Hoisting a load with a shackle or lifting lug made from an unrated steel at -30 C risks brittle fracture with no warning.
A millwright must replace a broken drive shaft. The old shaft is marked 4140, a magnet sticks strongly to it, and a file will barely cut the surface. What does this tell them about the material and its repair?
It is a low-carbon mild steel that can be welded freely without preheat
It is a grey cast iron shaft that must be brazed rather than welded
It is an austenitic stainless steel that cannot be hardened, so any similar bar stock will do
It is a chromium-molybdenum alloy steel with about 0.40% carbon in a hardened and tempered condition, so it requires preheat if welded and must be replaced with equivalent heat-treated material
A pump shaft in a chloride-bearing process is non-magnetic and the maintenance history says it was ordered as 316. The plant wants it hardened to reduce sleeve wear. What is the correct response?
Explain that austenitic stainless cannot be hardened by heat treatment and that wear resistance must come from cold work, a hard-faced or ceramic-coated sleeve area, or a change of material
Nitride the shaft at 900 C and quench in oil
Re-specify the shaft in 304 to increase hardness
Quench and temper the shaft to 40 HRC as with any alloy steel
A millwright machines a nylon bushing to a tight running clearance in a dry heated shop, and it seizes on the shaft two weeks after installation in a wash-down area. What material property explains the failure?
Nylon has a lower coefficient of friction when wet, causing the shaft to grip
Nylon absorbs moisture and can swell by 2–3%, closing the clearance; acetal or UHMW would have been dimensionally stable
Nylon loses strength above room temperature and deformed under load
Nylon is electrically conductive and welded itself to the steel shaft
Sections you finish are checked off in the contents.